Capon, Brian’s team published research in Pure and Applied Chemistry in 59 | CAS: 17236-59-8

Pure and Applied Chemistry published new progress about 17236-59-8. 17236-59-8 belongs to alcohols-buliding-blocks, auxiliary class Thiophene,Alcohol, name is Thiophen-3-ol, and the molecular formula is C4H4OS, Quality Control of 17236-59-8.

Capon, Brian published the artcileSome studies on the tautomerism of heterocyclic and homocyclic compounds, Quality Control of 17236-59-8, the publication is Pure and Applied Chemistry (1987), 59(12), 1577-84, database is CAplus.

The following hydroxy derivatives of heterocyclic compounds have been generated in solution and characterized by 1H-NMR spectroscopy: 3-hydroxyfuran, 3-hydroxythiophene, 3-hydroxypyrrole, 3-hydroxy-1-methylpyrrole, 3-hydroxybenzofuran, 3-hydroxybenzothiophene, 3-hydroxyindole, 3-hydroxy-1-methylindole, 2-hydroxythiophene, 2-hydroxybenzothiophene, 2,5-dihydroxythiophene. The rate and equilibrium constants for their ketonization have been measured and are discussed. The following hydroxy derivatives of homocyclic compounds were also generated, characterized and investigated: 1-hydroxyindene, 2-hydroxyindene, 1-hydroxycyclohepta-1,3,5-triene, 3-hydroxycyclohepta-1,3,5-triene, hydroxycyclooctatetraene, and 3-hydroxycycloocta-1,3,5-triene. The mechanism of hydrolysis of heterocyclic Me ethers derived from furan, thiophene, 1-methylpyrrole and their benzo-derivatives has been investigated and a change in rate limiting step from C-protonation to nucleophilic attack by water on the intermediate cation detected.

Pure and Applied Chemistry published new progress about 17236-59-8. 17236-59-8 belongs to alcohols-buliding-blocks, auxiliary class Thiophene,Alcohol, name is Thiophen-3-ol, and the molecular formula is C4H4OS, Quality Control of 17236-59-8.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts