Blandamer, Michael J. published the artcileMechanism and solvent reorganization accompanying hydrolyses of anchimerically assisted alkyl halides in water, SDS of cas: 2588-77-4, the publication is Journal of the American Chemical Society (1969), 91(10), 2678-83, database is CAplus.
This paper deals with the problem of solvent reorganization, anchimeric assistance, and mechanism for hydrolysis of 9 alkyl halides where the neighboring group is -OH, -OMe, or -SMe. By using the temperature coefficient of the enthalpy as a gauge of relative solvent reorganization, we show that the transition state in the hydrolysis of those alkyl halides giving evidence of anchimeric assistance resembles that for an SN1 mechanism. This conclusion was supported in one case by 13C labeling experiments in spite of product analysis seemingly favoring SN2 nucleophilic displacement by the solvent.
Journal of the American Chemical Society published new progress about 2588-77-4. 2588-77-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is 2-Methyl-3-bromo-2-butanol, and the molecular formula is C5H11BrO, SDS of cas: 2588-77-4.
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