Barik, Chandan Kr published the artcileRuthenacyclic Carbamoyl Complexes: Highly Efficient Catalysts for Organosilane Hydrolysis, Safety of Triethylsilanol, the publication is European Journal of Inorganic Chemistry (2018), 2018(46), 4982-4986, database is CAplus.
The ruthenacyclic carbamoyl complexes [RuX{2-NHC(O)C5H3NR}(CO)2(NCMe)] (R = H and Me; X = Br and SC6H3-o,o-Me2) are excellent catalysts for the hydrolysis of organosilanes, particularly towards primary silanes, generating H under ambient conditions within seconds. These complexes are structural mimics of the [Fe]-hydrogenase active site and like the natural enzyme, a labile ligand at the 6th coordination site is essential to the catalytic activity.
European Journal of Inorganic Chemistry published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Safety of Triethylsilanol.
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