Satoh, Yasushi published the artcileA catalyst- and additive-free synthesis of alkoxyhydrosiloxanes from silanols and alkoxyhydrosilanes, Safety of Triethylsilanol, the publication is Chemical Communications (Cambridge, United Kingdom) (2020), 56(59), 8218-8221, database is CAplus and MEDLINE.
A convenient method for the selective synthesis of alkoxyhydrosiloxanes that bear SiH and SiOR2 groups on the same silicon atom, R13Si-O-SiR32-n(OR2)nH (n = 0, 1, or 2), via a simple catalyst- and additive-free dealcoholization reaction between silanols and alkoxyhydrosilanes has been developed. These alkoxyhydrosiloxanes can be easily converted into Si(OR2)3-containing siloxanes by zinc catalyzed alkoxylation and alkoxy-containing silphenylene polymers by platinum catalyzed hydrosilylation.
Chemical Communications (Cambridge, United Kingdom) published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Safety of Triethylsilanol.
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