Medina-Ramirez, Iliana E. published the artcileSilylated gallium and indium chalcogenide ring systems as potential precursors to ME (E = O, S) materials, Computed Properties of 597-52-4, the publication is Central European Journal of Chemistry (2013), 11(7), 1225-1238, database is CAplus.
The reaction of R3M (M = Ga, In) with HESiR’3 (E = O, S; R’3=Ph3, iPr3, Et3, tBuMe2) leads to the formation of (Me2GaOSiPh3)2 (1); (Me2GaOSitBuMe2)2 (2); (Me2GaOSiEt3)2 (3); (Me2InOSiPh3)2 (4); (Me2InOSitBuMe2)2 (5); (Me2InOSiEt3)2 (6); (Me2GaSSiPh3)2 (7); (Et2GaSSiPh3)2 (8); (Me2GaSSiiPr3)2 (9); (Et2GaSSiiPr3)2 (10); (Me2InSSiPh3)3 (11); (Me2InSSiiPr3)n (12), in high yields at room temperature The compounds have been characterized by multinuclear NMR and in most cases by x-ray crystallog. The mol. structures of (1), (4), (7) and (8) have been determined Compounds (3), (6) and (10) are liquids at room temperature In the solid state, (1), (4), (7) and (9) are dimers with central core of the dimer being composed of a M2E2 four-membered ring. VT-NMR studies of (7) show facile redistribution between four- and six-membered rings in solution The thermal decomposition of (1)-(12) was examined by TGA and range from 200 to 350°. Bulk pyrolysis of (1) and (2) led to the formation of Ga2O3; (4) and (5) In metal; (7)-(10) GaS and (11)-(12) InS powders, resp.
Central European Journal of Chemistry published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Computed Properties of 597-52-4.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts