Paul, Aparup’s team published research in Polyhedron in 157 | CAS: 96-20-8

Polyhedron published new progress about 96-20-8. 96-20-8 belongs to alcohols-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Alcohol, name is 2-Aminobutan-1-ol, and the molecular formula is C4H11NO, Category: alcohols-buliding-blocks.

Paul, Aparup published the artcileDouble μ2-(phenoxido)-bridged dinuclear and polynuclear nickel(II) complexes: Magnetic properties and DNA/protein interaction, Category: alcohols-buliding-blocks, the publication is Polyhedron (2019), 39-48, database is CAplus.

One dinuclear and one 1-dimensional polymeric Ni(II) complex, {[Ni2(HL)2(pa)2(H2O)2]·DMF} (1) and {[Ni2(HL)2(ppda)(H2O)2]·DMF·H2O}n (2) (H2L = (E)-2-((1-hydroxybutan-2-ylimino)methyl)phenol, pa = 3-phenylacrylate, ppda = p-phenylenediacrylate) were synthesized and characterized by x-ray single crystal structure determination Complex 1 is double phenoxo-bridged dinuclear Ni(II) complex, whereas complex 2 is a 1-dimensional polynuclear chain where double phenoxo-bridged dinuclear units are connected through bridging ppda ligands. The variable temperature magnetic behavior of the complexes was studied using the Hamiltonian H = -JS1S2, S1 = S2 = SNi and confirms the presence of an overall antiferromagnetic interaction in both complexes. Good agreement between the exptl. and simulated curves were found using the parameters: gNi = 2.15, DNi = 4.0 cm-1 and JNi-Ni = -0.60 cm-1 for 1, and gNi = 2.15, DNi = 4.8 cm-1 and JNi-Ni = -3 cm-1 for 2. The interactions of the complexes with CT-DNA were studied using UV-visible absorption and fluorescence spectroscopic methods and both the complexes interact with CT-DNA. The intrinsic binding constants values for interaction with CT-DNA are 3.9(±0.10) × 105 and 3.43(±0.09) × 105 M-1 for 1 and 2, resp. The interactions of the complexes with bovine serum albumins (BSA) and human serum albumins (HSA) were also studied using electronic absorption and fluorescence spectroscopic techniques and both complexes interact with the serum albumins via a ground state association process.

Polyhedron published new progress about 96-20-8. 96-20-8 belongs to alcohols-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Alcohol, name is 2-Aminobutan-1-ol, and the molecular formula is C4H11NO, Category: alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts