Liang Teo, Alan Kay published the artcileA novel iron complex for highly efficient catalytic hydrogen generation from the hydrolysis of organosilanes, Name: Triethylsilanol, the publication is Chemical Communications (Cambridge, United Kingdom) (2014), 50(54), 7191-7194, database is CAplus and MEDLINE.
Hydrolytic oxidation of organosilanes based on an iron catalyst is described for the first time. The novel iron complex, [Fe(C6H5N2O)(CO)(MeCN)3][PF6], exhibits excellent mediating power in the catalytic hydrolysis of organosilanes to produce dihydrogen and organosilanols with turnover numbers approaching 104 and turnover frequencies in excess of 102 min-1 under ambient conditions.
Chemical Communications (Cambridge, United Kingdom) published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Name: Triethylsilanol.
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