Wang, Jianjun published the artcileTotal Synthesis of (-)-Melanthioidine by Copper-Mediated Cyclodimerization, Product Details of C9H11NO4, the publication is Organic Letters (2016), 18(15), 3542-3545, database is CAplus and MEDLINE.
An efficient asym. total synthesis of the dimeric macrocyclic diaryl ether phenethyltetrahydroisoquinoline alkaloid (-)-melanthioidine is reported. Key steps of the synthesis include an efficient Noyori asym. transfer hydrogenation to access the enantioenriched phenethyltetrahydroisoquinoline monomeric subunit and a copper-mediated cyclodimerization to form the two diaryl ether linkages with concomitant macrocyclization.
Organic Letters published new progress about 528594-30-1. 528594-30-1 belongs to alcohols-buliding-blocks, auxiliary class Nitro Compound,Benzene,Phenol,Ether, name is 2-Methoxy-4-(2-nitroethyl)phenol, and the molecular formula is C6H16OSi, Product Details of C9H11NO4.
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