Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 3452-97-9, Name is 3,5,5-Trimethylhexan-1-ol, molecular formula is , belongs to alcohols-buliding-blocks compound. In a document, author is Padmanaban, Sudakar, Recommanded Product: 3,5,5-Trimethylhexan-1-ol.
Chemoselective hydrogenation of alpha,beta-unsaturated carbonyl compounds using a recyclable Ru catalyst embedded on a bisphosphine based POP
Selective hydrogenation of the carbonyl functional group of alpha,beta-unsaturated carbonyl compounds affords industrially important allylic alcohols. However, achieving the selective reduction of the carbonyl group in the presence of the activated olefinic group is challenging. Therefore, the development of a highly chemoselective, efficient, and recyclable catalyst for this transformation is greatly desirable from the industrial and environmental viewpoints. In this study, a Ru-immobilized bisphosphine-based porous organic polymer (Ru@PP-POP) was used as an efficient heterogeneous catalyst for chemoselective hydrogenation of cinnamaldehyde (CAL) to cinnamyl alcohol with high chemoselectivity (98%) and excellent recyclability. To the best of our knowledge, the catalyst, Ru@PP-POP showed a high turnover number (970) and a high turnover frequency (240h(1)) which is the best activity obtained using a phosphine based heterogeneous Ru-catalyst in this transformation. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 3452-97-9, in my other articles. Recommanded Product: 3,5,5-Trimethylhexan-1-ol.
Reference:
Alcohol – Wikipedia,
,Alcohols – Chemistry LibreTexts