Wu, Yancong published the artcileZinc(II) and manganese(II) complexes with 1,3-bis(1-allylbenzimidazol-2-yl)-2-oxapropane: synthesis, crystal structures, antioxidant activities and DNA-binding properties, Computed Properties of 110-99-6, the main research area is zinc manganese allylbenzimidazolyloxapropane complex preparation crystal structure antioxidant; DNA interaction zinc manganese allylbenzimidazolyloxapropane complex.
Two new zinc(II) and manganese(II) complexes with the ligand 1,3-bis(1-allylbenzimidazol-2-yl)-2-oxopropane (aobb), with composition [Zn(aobb)2](pic)2·DMF·CH3OH and [Mn(aobb)(DMF)2(H2O)](pic)2 (pic = picrate; DMF = N,N-dimethylformamide), were synthesized and characterized by elemental anal., elec. conductivities, x-ray single-crystal diffraction, IR, and UV-visible spectra. Single-crystal x-ray revealed that Zn(II) and Mn(II) centers are both located in the six-coordinate distorted octahedral geometry. The DNA-binding modes of the ligand and the complexes were studied by electronic absorption titration, competitive binding with ethidium bromide and viscosity measurements. The exptl. evidence indicated the ligand and complexes interact with calf thymus DNA through intercalation. The binding strength follows the order >>aobb. Addnl., displays potential superoxide dismutase activity in vitro studies.
Journal of Coordination Chemistry published new progress about Antioxidants. 110-99-6 belongs to class alcohols-buliding-blocks, name is 2,2′-Oxydiacetic acid, and the molecular formula is C4H6O5, Computed Properties of 110-99-6.
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