Shibata, Mitsuhiro published the artcileBiobased polymer networks by the thiol-ene photopolymerization of allylated p-coumaric and caffeic acids, Application of Pentaerythritol tetra(3-mercaptopropionate), the main research area is biobased polymer network thiolene photopolymerization allylated coumarate caffeate.
Diallylated p-coumaric acid (A2CM) and triallylated caffeic acid (A3CF) were synthesized by the reactions of p-coumaric acid and caffeic acid with allyl bromide in the presence of potassium carbonate. The thiol-ene photopolymerization of A2CM and a pentaerythritol-based tetrathiol (S4P) as well as that of A3CF/S4P at allyl/thiol and (allyl + enone)/thiol ratios of 1/1 produced cured products. The FT-IR spectral anal. revealed that the thiol-ene reaction of allyl and thiol groups mainly progressed for the products cured at an allyl/thiol ratio of 1/1, while both allyl and enone groups reacted with thiol groups for the products cured at an (allyl + enone)/thiol ratio of 1/1. The progress of the thiol-ene reaction of the enone and thiol groups caused the lowering of the glass transition and 5% weight loss temperatures (Tg and Td5). The A3CF/S4P cured at an allyl/thiol ratio of 1/1 exhibited the highest Tg, Td5, tensile strength, and tensile modulus among all the cured products.
Polymer Journal (Tokyo, Japan) published new progress about Elongation at break. 7575-23-7 belongs to class alcohols-buliding-blocks, name is Pentaerythritol tetra(3-mercaptopropionate), and the molecular formula is C17H28O8S4, Application of Pentaerythritol tetra(3-mercaptopropionate).
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts