Blinkovsky, Alexander M. published the artcileEnzymic derivatization of saccharides and their chemical polymerization, Recommanded Product: (2R,3R,4S,5R,6R)-2-(Allyloxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol, the main research area is propargyl galactopyranoside preparation polymerization; allyl galactopyranoside preparation polymerization; hydrophilic polymer sugar; oligosaccharide transglycosidation enzymic propargyl allyl alc.
The enzymic synthesis of sugar-based acetylene and ethylene derivatives as precursors to hydrophilic polymers is described. Propargyl and allyl alcs. have been used as glycosyl acceptors in the transglycosylation reactions of glycosidases with various disaccharides including lactose, maltose, and cellobiose. Reaction of propargyl and allyl alcs. with lactose catalyzed by β-galactosidase resulted in the formation of propargyl-β-D-galactopyranoside and allyl-β-D-galactopyranoside in 42 and 13% yields, resp. Polymerization of propargyl-β-D-galactopyranoside with AlBr3 in ethanol resulted in the formation of oligomeric poly(acetylenic) species (MW = 1,300). Free radical polymerization of allyl-β-D-galactopyranoside in DMF or water resulted in poly(ethylenic) species with MW > 30,000. The combined enzymic and chem. reactions inherent in these syntheses provide a unique approach in the preparation of hydrophilic polymers containing sugars and their derivatives
Tetrahedron: Asymmetry published new progress about Disaccharides Role: RCT (Reactant), RACT (Reactant or Reagent). 2595-07-5 belongs to class alcohols-buliding-blocks, name is (2R,3R,4S,5R,6R)-2-(Allyloxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol, and the molecular formula is C9H16O6, Recommanded Product: (2R,3R,4S,5R,6R)-2-(Allyloxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol.
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Alcohols – Chemistry LibreTexts