Wang, Azhong published the artcilePalladium-Catalyzed Direct Oxidation of Alkenes with Molecular Oxygen: General and Practical Methods for the Preparation of 1,2-Diols, Aldehydes, and Ketones, Related Products of alcohols-buliding-blocks, the main research area is terminal disubstituted olefin oxygen base palladium dihydroxylation; diol preparation; oxygen terminal disubstituted olefin PTSA palladium oxidative cleavage; aldehyde Ketone preparation green chem reaction mechanism; dihydroxylation oxidative cleavage catalyst palladium.
Novel and environmentally benign methods for palladium-catalyzed dihydroxylation and oxidative cleavage of olefins with oxygen as sole oxidant are presented. The cleavage reactions were performed with acid as additive in aqueous solution, whereas 1,2-diols were formed in the presence of base. A broad substrate scope has been demonstrated allowing monosubstituted aromatic and aliphatic terminal alkenes, 1,2-disubstituted, and 1,1-disubstituted olefins. The cleavage reactions of dioxo-PdII complexes implicate 1,2-diol might act as a key intermediate of olefin cleavage.
Journal of Organic Chemistry published new progress about Aldehydes Role: SPN (Synthetic Preparation), PREP (Preparation). 92093-23-7 belongs to class alcohols-buliding-blocks, name is 1-(4-Bromophenyl)ethane-1,2-diol, and the molecular formula is C8H9BrO2, Related Products of alcohols-buliding-blocks.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts