Zhang, Qing published the artcileNi-Catalyzed Enantioselective Allylic Alkylation of H-Phosphinates, SDS of cas: 584-02-1, the main research area is nickel catalyzed enantioselective allylic alkylation phosphinate allylic acetate; stereogenic allylic phenyl phosphinate preparation crystal structure; mol structure stereogenic allylic phenyl phosphinate.
The asym. synthesis of P-stereogenic phosphinates through allylic alkylation of H-phosphinates was developed. With H-phosphinates and allylic acetates as the starting materials, a variety of allylic P-chiral phosphinates were accessed in high enantioselectivities of up to 92% ee and generally high yields. A further study demonstrated the applicability of this protocol, including the scale-up synthesis and facile transformation of chiral products from phosphinates to phosphine oxides with organolithium reagents under mild reaction conditions.
Organic Letters published new progress about Acetates Role: RCT (Reactant), RACT (Reactant or Reagent) (allylic). 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, SDS of cas: 584-02-1.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts