Qiu, Jikuan published the artcileCu(I)/ionic liquids promote the conversion of carbon dioxide into oxazolidinones at room temperature, Safety of 3,5-Dimethylhex-1-yn-3-ol, the main research area is oxazolidinone preparation green chem; propargylic alc amine carbon dioxide three component copper catalyst; carbon dioxide; catalysis; ionic liquids; oxazolidinones.
A one-pot three component reaction of propargylic alcs. HOC(R1)(R2)CCH [R1 = Me, Et, isobutyl; R2 = Me; R1 = R2 = -(CH2)5-], amines R3NH2 (R3 = n-Bu, iso-Bu, cyclohexyl, n-hexyl) and CO2 that can proceed in an atom economy and environmentally benign manner by combination of CuI and tetrabutylphosphonium imidazol ([P4444][Im]) as a catalyst was described. Catalysis studies indicate that this catalytic system is an effective catalyst for the conversion of CO2 into oxazolidinones I at room temperature and ambient pressure without any solvent. The results provide a useful way to design novel noble metal-free catalyst systems for the transformation of CO2 into other valuable compounds
Molecules published new progress about Alcohols, propargyl Role: RCT (Reactant), RACT (Reactant or Reagent). 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, Safety of 3,5-Dimethylhex-1-yn-3-ol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts