Determination of characteristic factors of the rate of migration of a group between vicinal carbon atoms was written by Yvernault, Theophile;Mazet, Michel. And the article was included in Comptes Rendus des Seances de l’Academie des Sciences in 1969.Synthetic Route of C9H20O2 The following contents are mentioned in the article:
The total 1st order rate constants for the rearrangement of HOCH2CR1RCH2OH to HOCH2CR(OH)CH2R1 (R and R1 are Me, Et, Pr, Bu, Bz, and Ph) were determined by azeotropic distillation The migration rate appears, as a 1st approximation, to be the product of 2 independent factors: the migratory power of the group, and an assistance factor of the adjacent group. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Synthetic Route of C9H20O2).
2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Synthetic Route of C9H20O2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts