Highly Acidic BINOL-Derived Phosphoramidimidates and their Application in the Bronsted Acid Catalyzed Synthesis of α-Tocopherol was written by Kaib, Philip S. J.;List, Benjamin. And the article was included in Synlett in 2016.Application of 851615-07-1 The following contents are mentioned in the article:
The design and synthesis of highly acidic BINOL-derived N,N’-bistriflylphosphoramidimidate and N,N’-bisarylsulfonylphosphoramidimidate Bronsted acid catalysts are reported. Thus, freshly prepared phosphoramidimidate I catalyzed the diastereoselective addition of trimethylhydroquinone to (7R,11R)-isophytol to give α-tocopherol with a diastereomeric ratio of 66:34. This study involved multiple reactions and reactants, such as (R)-[1,3′:1′,1”:3”,1”’-Quaternaphthalene]-2′,2”-diol (cas: 851615-07-1Application of 851615-07-1).
(R)-[1,3′:1′,1”:3”,1”’-Quaternaphthalene]-2′,2”-diol (cas: 851615-07-1) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Application of 851615-07-1
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts