Rh(III)-Catalyzed three-component C-H functionalization reaction with vinylene carbonate: Late-stage C-H esterification of indole derivatives was written by Li, Bin-Shi;Guo, Huai-Xuan;Sun, Wei;Sun, Meng. And the article was included in Tetrahedron Letters in 2022.Name: 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:
An efficient and robust Rh(III)-catalyzed three-component C-H esterification reaction of indole derivatives with vinylene carbonate to access indolyl acetates was developed. This protocol exhibited high efficiency, good yields and excellent functional group tolerance. Significantly, this method provided a powerful approach for the late-stage modification of indole-based substrates and natural alcs. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Name: 3,7-Dimethyloctan-1-ol).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Name: 3,7-Dimethyloctan-1-ol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts