Direct formation of oxetanes by pyrolysis of diprimary diols in the presence of catalysts was written by Jaubert, Michele;Mazet, Michel;Yvernault, Theophile. And the article was included in Bulletin de la Societe Chimique de France in 1974.Application of 115-84-4 The following contents are mentioned in the article:
Oxetanes I (R = Et, Pr, Bu, CHMe2, H, Me; R1 = H, Me, Et, Pr, Bu, CHMe2, CMe3, CHPrMe, CHPrEt, (CH2)4Me) were prepared in ≤24% yield by pyrolyzing RR1C(CH2OH)2, the acetals II, or the formals III in the presence of pumice at 350°. A pumice-diol ratio of 5 gave the highest yields. The yields of I also increased with the size of R and R1. Pyrolysis of I (R = R1 = Et) gave Et2CHCHO, Et2C:CH2, EtPrCHCHO, EtMeCHCOEt, PrMeCHCOMe. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Application of 115-84-4).
2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Application of 115-84-4
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts