A convenient biphasic process for the monosilylation of symmetrical 1,n-primary diols was written by Yu, Chengzhi;Liu, Bin;Hu, Longqin. And the article was included in Tetrahedron Letters in 2000.SDS of cas: 115-84-4 The following contents are mentioned in the article:
A simple and mild biphasic process was developed for the selective protection of one of two chem. equivalent primary hydroxyl groups in 1,n-diols using t-butyldiphenyl silyl chloride in diisopropyl Et amine (DIEA) and DMF. E.g., a solution of 2-Butyl-2-ethylpropanediol in DMF (3 mL) was charged with DIEA (10 equiv), to which mixture was added TBDPSCl (1.05 equiv) with stirring to give the corresponding monosilylated product in 92% yield. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4SDS of cas: 115-84-4).
2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.SDS of cas: 115-84-4
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts