Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles was written by Kobayashi, Masaki;Yamaguchi, Hiroki;Suzuki, Takeyuki;Obora, Yasushi. And the article was included in Organic & Biomolecular Chemistry in 2021.Synthetic Route of C10H22O The following contents are mentioned in the article:
A simple method for the cross β-alkylation of linear alcs. R(CH2)2OH (R = octyl, cyclohexylmethyl, Ph, 3-benzyl-4-hydroxybutyl, etc.) with benzyl alcs. R1CH2OH (R1 = Ph, cyclopropyl, thiophen-2-yl, etc.) in the presence of DMF-stabilized iridium nanoparticles was developed. The nanoparticles were prepared in one-step and thoroughly characterized. Furthermore, the optimum reaction conditions have a wide substrate scope and excellent product selectivity. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Synthetic Route of C10H22O).
3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Synthetic Route of C10H22O
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts