Kumar, Shreemoyee published the artcileRu(II)-catalyzed allenylation and sequential annulation of N-tosylbenzamides with propargyl alcohols, Recommanded Product: 3,5-Dimethylhex-1-yn-3-ol, the main research area is allenylamide isoquinolone preparation; tosylbenzamide propargyl alc allenylation sequential annulation ruthenium catalyst.
Here Ru(II)-catalyzed C(sp2)-H allenylation of N-tosylbenzamides to access multi-substituted allenylamides has been reported. Furthermore, the allenylamides were converted to the corresponding isoquinolone derivatives via base mediated annulation. The current protocol features low catalyst loading, mild reaction conditions, high functional group compatibility and desired scalability. The unique functionality of the afforded allenes allowed further transformations to expand the practicality of the protocol.
Chemical Communications (Cambridge, United Kingdom) published new progress about Allenes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, Recommanded Product: 3,5-Dimethylhex-1-yn-3-ol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts