Pal, Ritashree published the artcileAmidoaldehydes as Substrates in Rhodium-Catalyzed Intermolecular Alkyne Hydroacylation: The Synthesis of α-Amidoketones, Application In Synthesis of 22483-09-6, the main research area is amido aldehyde alkyne rhodium catalyst regioselective hydroacylation; oxo propanamide preparation; aldehyde; alkyne; catalysis; hydroacylation; rhodium.
Readily available α-amidoaldehydes were effective substrates for intermol. Rh-catalyzed alkyne hydroacylation reactions. The catalyst [Rh(dppe)(C6H5F)][BArF4] provided good reactivity, and allowed a broad range of aldehydes and alkynes to be used as substrates, delivering α-amidoketone products. High yields and high levels of regioselectivity were achieved. The use of α-amidoaldehydes as substrates establishes that 1,4-dicarbonyl motifs was used as controlling groups in Rh-catalyzed hydroacylation reactions.
Chemistry – A European Journal published new progress about Aldehydes Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 22483-09-6 belongs to class alcohols-buliding-blocks, name is 2,2-Dimethoxyethanamine, and the molecular formula is C4H11NO2, Application In Synthesis of 22483-09-6.
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