Li, Yiming published the artcileSelective Late-Stage Oxygenation of Sulfides with Ground-State Oxygen by Uranyl Photocatalysis, COA of Formula: C4H10OS, the main research area is photooxidation catalyst uranyl sulfide sulfoxide sulfone; oxygen; oxygenation; photocatalysis; sulfides; uranyl catalysis.
Oxygenation is a fundamental transformation in synthesis. Herein, we describe the selective late-stage oxygenation of sulfur-containing complex mols. with ground-state oxygen under ambient conditions. The high oxidation potential of the active uranyl cation (UO22+) enabled the efficient synthesis of sulfones. The ligand-to-metal charge transfer process (LMCT) from O 2p to U 5f within the O::U::O group, which generates a UV center and an oxygen radical, is assumed to be affected by the solvent and additives, and can be tuned to promote selective sulfoxidation This tunable strategy enabled the batch synthesis of 32 pharmaceuticals and analogs by late-stage oxygenation in an atom- and step-efficient manner.
Angewandte Chemie, International Edition published new progress about Cell proliferation. 505-10-2 belongs to class alcohols-buliding-blocks, name is 3-(Methylthio)propan-1-ol, and the molecular formula is C4H10OS, COA of Formula: C4H10OS.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts