Park, Hea Jung published the artcileNew blue phosphorescent heteroleptic Ir(III) complexes with imidazole- and N-methylimidazole carboxylates as ancillary ligands, Computed Properties of 22483-09-6, the main research area is spirocyclic phenylpyridinyl iridacycle imidazolecarboxylate preparation electrochem OLED phosphorescence; crystal structure spirocyclic phenylpyridinyl iridacycle imidazolecarboxylate; mol structure spirocyclic phenylpyridinyl iridacycle imidazolecarboxylate.
Imidazole- and N-methylimidazole carboxylate were introduced to serve as ancillary ligands in heteroleptic Ir(III) complexes containing 2-phenylpyridine-based main ligands, with consideration of the frontier orbital energy levels. Complexes Ir1-Ir4 were synthesized and found to have LUMO levels higher than that of the corresponding Ir(III) complex containing pyridyl carboxylate. All the synthesized Ir(III) complexes exhibited blue phosphorescence emission maxima at 465-467 nm at room temperature Phosphorescent quantum efficiencies were increased by a factor of 1.8-6.7 by blocking the intermol. H bonding between the imidazole carboxylate ligands of neighboring Ir(III) complexes, which was achieved by N-methylation of the imidazole carboxylate ancillary ligand. The organic light-emitting diodes fabricated using Ir3 and Ir4 as dopant materials in the emissive layers emit blue emission with peaks at 469 and 471 nm and maximum external quantum efficiencies of 20.0 and 22.4%, resp. Also, all the fabricated devices with Ir3 and Ir4 exhibited low efficiency roll-off, indicating excellent stability of the materials.
Journal of Materials Chemistry C: Materials for Optical and Electronic Devices published new progress about Carboxylic esters Role: PEP (Physical, Engineering or Chemical Process), PRP (Properties), SPN (Synthetic Preparation), PROC (Process), PREP (Preparation) (spirocyclic iridacycle imidazolecarboxylates). 22483-09-6 belongs to class alcohols-buliding-blocks, name is 2,2-Dimethoxyethanamine, and the molecular formula is C4H11NO2, Computed Properties of 22483-09-6.
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