Botubol-Ares, Jose Manuel published the artcileMethylene-Linked Bis-NHC Half-Sandwich Ruthenium Complexes: Binding of Small Molecules and Catalysis toward Ketone Transfer Hydrogenation, Formula: C10H12ClNO, the publication is Organometallics (2021), 40(6), 792-803, database is CAplus.
[Cp*RuCl(COD)] reacts with LH2Cl2 (L = methanebis(3-methylimidazol-2-ylidene)) and LiBu in THF at 65° furnishing the bis-carbene derivative [Cp*RuCl(L)] (2). This compound reacts with NaBPh4 in MeOH under dinitrogen to yield the labile dinitrogen-bridged complex [{Cp*Ru(L)}2(μ-N2)][BPh4]2 (4). The dinitrogen ligand in 4 is readily replaced by donor mols. leading to the corresponding cationic complexes [Cp*Ru(X)(L)][BPh4] (X = MeCN 3, H2 (6), C2H4 (8a), CH2CHCOOMe 8b, CHPh 9). Attempts to recrystallize 4 from MeNO2/EtOH solutions gave the nitrosyl derivative [Cp*Ru(NO)(L)][BPh4]2 (5), which was structurally characterized. The allenylidene complex [Cp*Ru:C:C:CPh2(L)][BPh4] (10) was also obtained, and it was prepared by reaction of 2 with HCCC(OH)Ph2 and NaBPh4 in MeOH at 60°. 3, 4, And 6 are efficient catalyst precursors for the transfer hydrogenation of a broad range of ketones. The dihydrogen complex 6 proved particularly effective, reaching TOF values up to 455 h-1 at catalyst loadings of 0.1% mol., with a high functional group tolerance on the reduction of a broad scope of aryl and aliphatic ketones to yield the corresponding alcs.
Organometallics published new progress about 1310357-40-4. 1310357-40-4 belongs to alcohols-buliding-blocks, auxiliary class Benzenes, name is 7-Chloro-2,3,4,5-tetrahydro-1H-benzo[b]azepin-5-ol, and the molecular formula is C10H12ClNO, Formula: C10H12ClNO.
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