Dhiman, Mahak published the artcileOrganosilane oxidation with a half million turnover number using fibrous nanosilica supported ultrasmall nanoparticles and pseudo-single atoms of gold, Synthetic Route of 597-52-4, the publication is Journal of Materials Chemistry A: Materials for Energy and Sustainability (2017), 5(5), 1935-1940, database is CAplus.
The combination of ultrasmall nanoparticles and pseudo-single atoms of gold (Au) and fibrous nanosilica (KCC-1) functionalized with 3-aminopropyltriethoxysilane (APTS) enabled the design of KCC-1-APTS/Au nanocatalysts with very high turnover numbers (TONs). KCC-1-APTS/Au catalyzed the oxidation of organosilanes to silanols, with a TON of approx. half a million (591 000 for dimethylphenyl silane as a model substrate). Addnl., the figure-of-merit (FOM), which provides an integrated view of the rate of the reaction, the energy required, the reaction scale and the recyclability of the catalysts, was 633 mmol h-1 K-1. KCC-1-APTS/Au also catalyzed two addnl. challenging reactions, the alcoholysis of silane and the hydrosilylation of aldehydes, with very high TONs. These characteristics make KCC-1-APTS/Au a versatile nanocatalyst.
Journal of Materials Chemistry A: Materials for Energy and Sustainability published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Synthetic Route of 597-52-4.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts