Lenca, Nicole published the artcileEstimation of descriptors for hydrogen-bonding compounds from chromatographic and liquid-liquid partition measurements, Application In Synthesis of 122-20-3, the publication is Journal of Chromatography A (2017), 13-22, database is CAplus and MEDLINE.
Retention factors obtained by gas chromatog. and reversed-phase liquid chromatog. on varied columns and partition constants in different liquid-liquid partition systems were used to estimate WSU descriptor values for 36 anilines and N-heterocyclic compounds, 13 amides and related compounds, and 45 phenols and alcs. These compounds are suitable for use as calibration compounds to characterize separation systems covering the descriptor space E = 0.2-3, S = 0.4-2.1, A = 0-1.5, B = 0.1-1.5, L = 2.5-10.0 and V = 0.5-2.2. Hydrogen-bonding properties are discussed in terms of structure, the possibility of induction effects, intramol. hydrogen bonding and steric factors for anilines, amides, phenols and alcs. The relation between these parameters and observed descriptor values are difficult to predict from structure but facilitate improving the general occupancy of the descriptor space by creating incremental changes in hydrogen-bonding properties. It is verified that the compounds included in this study can be merged with an existing database of compounds recommended for characterizing separation systems.
Journal of Chromatography A published new progress about 122-20-3. 122-20-3 belongs to alcohols-buliding-blocks, auxiliary class Organic Pigment, name is Triisopropanolamine, and the molecular formula is C9H21NO3, Application In Synthesis of 122-20-3.
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