Syntheses, crystal structures, spectral studies, and DFT calculations of two new square planar Ni(II) complexes derived from pyridoxal-based Schiff base ligands was written by Mandal, Senjuti;Chatterjee, Sudipta;Modak, Ritwik;Sikdar, Yeasin;Naskar, Barnali;Goswami, Sanchita. And the article was included in Journal of Coordination Chemistry in 2014.Synthetic Route of C8H10ClNO3 The following contents are mentioned in the article:
Two new complexes based on a Schiff base derived from pyridoxal N,N-dimethylethylenediamine (HL1) and N,N-diethylethylenediamine (HL2), [Ni(L1)SCN] and [Ni(L2)SCN], were synthesized and structurally characterized by single-crystal x-ray diffraction along with other phys. techniques, including elemental analyses, IR spectra, cyclic voltammetry, UV-visible, and luminescence studies. X-ray studies suggest that in both the complexes Ni lies in a slightly distorted square planar environment occupied by the tridentate ONN ligand and an isothiocyanate moiety. D. functional theory computations were carried out to characterize the complexes. This study involved multiple reactions and reactants, such as 3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5Synthetic Route of C8H10ClNO3).
3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Synthetic Route of C8H10ClNO3
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