Synthesis of some 1,1,1-tris(hydroxymethyl)alkanes was written by Weibull, Bengt;Matell, Magnus. And the article was included in Acta Chemica Scandinavica in 1962.Application of 115-84-4 The following contents are mentioned in the article:
By condensing 0.4 mole aldehyde with 3 moles HCHO in 500 ml. 1:1 aqueous EtOH and adding 0.4 mole KOH in 200 ml. 1:1 aqueous EtOH dropwise with cooling, the following 1,1,1-tris(hydroxymethyl)alkanes [R of RC(CH2-OH)3, % yield, b.p.(mm.), and m.p. (crystallization solvent), resp., given] were prepared: C5H11, 61, 160-2° (1.5), 64-5.5°(CCl4); C6H13, -, – (-), 68-70° (CHCl3); C8H17, 65, 190-200° (1.5), 73.5-5° (ligroine); C9H19, 47, 187-90° (1), 77-9° (ligroine); C10H21, 45, 180-6° (0.3), 79.5-81° (ligroine); and C12H25, 51, 200-20° (2.5), 83-8° (ligroine). Similarly prepd, was 3,3-bis(hydroxymethyl)heptane, 83, 136-43° (8), 40-2.5° (-). This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Application of 115-84-4).
2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Application of 115-84-4
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts