Diverse reactivity to hypochlorite and copper ions based on a novel Schiff base derived from vitamin B6 cofactor was written by Li, Xiangqian;Wen, Qin;Gu, Jiapei;Liu, Wanqiang;Wang, Qianming;Zhou, Guofu;Gao, Jinwei;Zheng, Yuhui. And the article was included in Journal of Molecular Liquids in 2020.Electric Literature of C8H10ClNO3 The following contents are mentioned in the article:
A new Schiff base receptor (2-amino-3-(((3-hydroxy-5-(hydroxymethyl)-2-methylpyridin-4-yl)methylene) amino)maleonitrile) has been synthesized. Such diaminomaleonitrile-based mol. framework is observed to be water soluble GAL possesses both colorimetric and off-on fluorescent response in the presence of ClO– . The response time has been controlled within 6min.The limit of detection has been calculated to be 47.5nM. The addition of Cu2+ can only induce clear color evolution from pale to deep yellow and no fluorescence changes are found. Moreover, its reliability and practicality are verified via the determination of ClO– in spiked samples of tap water and pond water. The exploration of bioactive vitamin B6 cofactor as a sensing platform will open a new way for multiple target recognition in competitive medium. This study involved multiple reactions and reactants, such as 3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5Electric Literature of C8H10ClNO3).
3-Hydroxy-5-(hydroxymethyl)-2-methylisonicotinaldehyde hydrochloride (cas: 65-22-5) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Electric Literature of C8H10ClNO3
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts