Mechanism of chromic acid oxidation. III. The oxidation of diols was written by Kwart, Harold;Ford, J. A. Jr.;Corey, G. C.. And the article was included in Journal of the American Chemical Society in 1962.Quality Control of 2-Butyl-2-ethylpropane-1,3-diol The following contents are mentioned in the article:
cf. CA 54, 6505a; 56, 7111c. The earlier interpretations of Rocek (CA 54, 13833a) and Favre (CA 53, 18084d) of the rates of chromic acid oxidation of diols were found to be misleading, in view of conformational and structural effects which govern the reactivity. The occurrence of cyclic chromate esters as intermediates in the oxidation of certain diol structures but not of others was inferred from rate data obtained for a variety of bicyclic, alicyclic, and acyclic 1,2- and 1,3-diols. In this fashion also, the geometric requirements for such cyclic chromate ester formation were found to be similar to those deduced earlier for boric acid complexing with diols. It was suggested that the formation of esters by interaction of chromic acid with alcs. was quite analogous to ester formation with boric rather than sulfuric acid, as claimed by Rocek. This study involved multiple reactions and reactants, such as 2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4Quality Control of 2-Butyl-2-ethylpropane-1,3-diol).
2-Butyl-2-ethylpropane-1,3-diol (cas: 115-84-4) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Quality Control of 2-Butyl-2-ethylpropane-1,3-diol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts