Ultrasound-assisted adsorption/desorption of jujube peel flavonoids using macroporous resins was written by Shen, Dongbei;Labreche, Faiza;Wu, Caie;Fan, Gongjian;Li, Tingting;Dou, Jinfeng;Zhu, Jinpeng. And the article was included in Food Chemistry in 2022.Safety of (2R,2’R,3R,3’R,4R)-2,2′-Bis(3,4-dihydroxyphenyl)-[4,8′-bichromane]-3,3′,5,5′,7,7′-hexaol The following contents are mentioned in the article:
The work explored the process of ultrasound-assisted adsorption/desorption to efficiently purify jujube peel flavonoids (JPFs) using macroporous resins (MRs). The impact of ultrasound power and temperature on the adsorption/desorption features of JPFs on MRs were studied. The maximum adsorption (80.21 ± 2.11 mg/g) /desorption (76.22 ± 1.68 mg/g) capacity of total flavonoids content were obtained. The pseudo-second-order kinetic and Freundlich isotherm models better described the whole process of ultrasound-assisted adsorption. The adsorption process was spontaneous, phys., and dominated by multilinear intraparticle diffusion. Ultrasound mainly enhanced the adsorption capacity by strengthening the formation of hydrogen bonds and increasing the surface roughness of MRs. Besides, the principal individual flavonoid ((+)-Catechin, (-)-Epicatechin, Rutin, Quercetin-3-O-robinobioside) content of JPFs in ultrasound treatment was 2-3 times that of shaking treatment, and biol. activities were significantly increased. Overall, as a low-cost green technol., ultrasound can improve the properties of MRs and better purify JPFs. This study involved multiple reactions and reactants, such as (2R,2’R,3R,3’R,4R)-2,2′-Bis(3,4-dihydroxyphenyl)-[4,8′-bichromane]-3,3′,5,5′,7,7′-hexaol (cas: 29106-49-8Safety of (2R,2’R,3R,3’R,4R)-2,2′-Bis(3,4-dihydroxyphenyl)-[4,8′-bichromane]-3,3′,5,5′,7,7′-hexaol).
(2R,2’R,3R,3’R,4R)-2,2′-Bis(3,4-dihydroxyphenyl)-[4,8′-bichromane]-3,3′,5,5′,7,7′-hexaol (cas: 29106-49-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Safety of (2R,2’R,3R,3’R,4R)-2,2′-Bis(3,4-dihydroxyphenyl)-[4,8′-bichromane]-3,3′,5,5′,7,7′-hexaol
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