《Chromium-catalyzed linear-selective alkylation of aldehydes with alkenes》 was published in Organic Letters in 2020. These research results belong to Hirao, Yuki; Katayama, Yuri; Mitsunuma, Harunobu; Kanai, Motomu. Application In Synthesis of 5-Hexen-1-ol The article mentions the following:
We developed a chromium-catalyzed, photochem., and linear-selective alkylation of aldehydes with alkylzirconium species generated in situ from a wide range of alkenes and Schwartz’s reagent. Photochem. homolysis of the C-Zr bond afforded alkyl radicals, which were then trapped by a chromium complex catalyst to generate the alkylchromium(III) species for polar addition to aldehydes. The reaction proceeded with high functional group tolerance at ambient temperature under visible-light irradiation In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Application In Synthesis of 5-Hexen-1-ol)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Application In Synthesis of 5-Hexen-1-ol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts