Wu, Peng-yu; Lu, Guo-ping; Cai, Chun published an article in 2021. The article was titled ãSynthesis of an Fe-Pd bimetallic catalyst for N-alkylation of amines with alcohols via a hydrogen auto-transfer methodologyã? and you may find the article in Green Chemistry.Product Details of 873-75-6 The information in the text is summarized as follows:
Hydrogen auto-transfer (HAT) or borrowing hydrogen (BH) methodol. which combines dehydrogenation, intermediate reaction and hydrogenation, is recognized as an excellent strategy for one-pot synthesis from an economic and environmental point of view. Although much effort has been made on the development of catalysts for HAT reactions, harsh conditions, external base or large amounts of noble metals are still required in most reported catalysis systems, and thus the exploration of a highly efficient and recyclable heterogeneous catalyst remains meaningful. In this work, a novel bimetallic catalyst, Fe10Pd1/NC500 derived from bimetallic MOF NH2-MIL-101(Fe10Pd1), has been prepared, and the catalyst exhibits superior catalytic performance for the N-alkylation of amines with alcs. via a hydrogen auto-transfer methodol. High yields of the desired products were achieved at 120° with an alc./amine molar ratio of 2 : 1 and required no external additive or solvent. A distinct enhancement in catalytic performance is observed when compared with monometallic catalysts, which can be ascribed to the “”synergistic effects”” inside the bimetallic alloys. The N-doped carbon support has been revealed to provide the necessary basicity which avoids the requirement of an external base. Moreover, a wide substrate range and remarkable reusability have been shown by Fe10Pd1/NC500, and this work highlights new possibilities for bimetallic catalysts applied in sustainable chem.(4-Bromophenyl)methanol(cas: 873-75-6Product Details of 873-75-6) was used in this study.
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Product Details of 873-75-6 It is used in the synthesis of amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts