Product Details of 873-75-6In 2021 ,ãNickel-Catalyzed Guerbet Type Reaction: C-Alkylation of Secondary Alcohols via Double (de)Hydrogenationã?was published in Organic Letters. The article was written by Babu, Reshma; Subaramanian, Murugan; Midya, Siba P.; Balaraman, Ekambaram. The article contains the following contents:
Acceptorless double dehydrogenative cross-coupling of secondary and primary alcs. under nickel catalysis is reported. This Guerbet type reaction provides an atom- and a step-economical method for the C-alkylation of secondary alcs. under mild, benign conditions. A broad range of substrates including aromatic, cyclic, acyclic, and aliphatic alcs. was well tolerated. Interestingly, the C-alkylation of cholesterol derivatives and the double C-alkylation of cyclopentanol with various alcs. were also demonstrated. The experimental part of the paper was very detailed, including the reaction process of (4-Bromophenyl)methanol(cas: 873-75-6Product Details of 873-75-6)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Product Details of 873-75-6 It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts