Electric Literature of C7H7BrOIn 2020 ,ãA Highly Selective Manganese-Catalyzed Synthesis of Imines under Phosphine-Free Conditionsã?appeared in Organometallics. The author of the article were Chai, Huining; Yu, Kun; Liu, Bo; Tan, Weiqiang; Zhang, Guangyao. The article conveys some information:
An efficient and highly selective phosphine-free NN-Mn(I) complex catalyst system was developed for the acceptorless dehydrogenative coupling of alcs. with amines to form imines. The coupling reactions underwent at 3 mol% catalyst loading, and a large range of alcs. and amines with diverse functional groups was applied, including challenging diol and diamine. The target imine products were obtained in good to excellent yields. The present work provides an alternative method to construct highly active nonprecious metal complex catalysts based on phosphine-free ligands. In the experimental materials used by the author, we found (4-Bromophenyl)methanol(cas: 873-75-6Electric Literature of C7H7BrO)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Electric Literature of C7H7BrO It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
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