Synthetic Route of C7H7BrOIn 2019 ,ãTemperature responsive polymer-supported TEMPO: An efficient and recoverable catalyst for the selective oxidation of alcoholsã?was published in Tetrahedron Letters. The article was written by Chen, Tao; Xu, Zhenkai; Zhou, Lei; Hua, Laiyu; Zhang, Shuo; Wang, Jiping. The article contains the following contents:
This study aimed to combine the advantages of homogeneous catalysis and heterogeneous catalysis by immobilizing TEMPO into a water-soluble temperature responsive polymer. The supported TEMPO was water soluble and displayed excellent activity in the selective oxidation of alcs. below the LCST and can be easily recovered. The results came from multiple reactions, including the reaction of (4-Bromophenyl)methanol(cas: 873-75-6Synthetic Route of C7H7BrO)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Synthetic Route of C7H7BrO It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts