ãLuminescent tungsten(VI) complexes as photocatalysts for light-driven C-C and C-B bond formation reactionsã?was written by Yu, Daohong; To, Wai-Pong; Tong, Glenna So Ming; Wu, Liang-Liang; Chan, Kaai-Tung; Du, Lili; Phillips, David Lee; Liu, Yungen; Che, Chi-Ming. SDS of cas: 24388-23-6 And the article was included in Chemical Science in 2020. The article conveys some information:
The realization of photocatalysis for practical synthetic application hinges on the development of inexpensive photocatalysts which can be prepared on a large scale. Herein an air-stable, visible-light-absorbing photoluminescent tungsten(VI) complex which can be conveniently prepared at the gram-scale is described. This complex could catalyze photochem. organic transformation reactions including borylation of aryl halides R1X (X = Cl, Br, I; R1 = 4-[ethoxy(oxo)methane]phenyl, naphthalen-2-yl, 3,5-dimethylphenyl, etc.), reductive coupling of benzyl bromides R2CH2Br (R2 = Ph, 3,4-dimethoxyphenyl, 2-bromophenyl, etc.) for C-C bond formation, reductive coupling of phenacyl bromides R3C(O)CH2Br (R3 = Ph, 4-fluorophenyl, 2-methoxyphenyl, 3,5-bis(trifluoromethyl)phenyl) and decarboxylative coupling of redox-active esters of alkyl carboxylic acid with high product yields and broad functional group tolerance. In the part of experimental materials, we found many familiar compounds, such as 4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane(cas: 24388-23-6SDS of cas: 24388-23-6)
4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane(cas: 24388-23-6) also known as boronate ester, is generally used in metal-catalyzed C-C bond formation reactions like Suzuki–Miyaura reaction.SDS of cas: 24388-23-6
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