In 2019,RSC Advances included an article by Walia, Preet Kamal; Sharma, Manik; Kumar, Manoj; Bhalla, Vandana. Related Products of 873-75-6. The article was titled 《UV light promoted ‘Metal’/’Additive’-free oxidation of alcohols: investigating the role of alcohols as electron donors》. The information in the text is summarized as follows:
UV light promoted selective oxidation of primary and secondary alcs. RCH(R1)OH [R = Ph, cyclohexyl, thiophen-2-yl, etc.; R1 = H, Ph, Me; RR1 = -(CH2)5-], 1,3-benzenedimethanol and 9H-fluoren-9-ol has been demonstrated under ‘metal-free’ and ‘additive-free’ conditions. Under the optimized conditions, a variety of aromatic, heteroaromatic, and alicyclic alcs. have been examined for their transformations to the corresponding carbonyl compounds RC(O)R1, isophthalaldehyde and 9H-fluoren-9-one. The mechanistic studies emphasize the important role of substrate (alc.) and solvent (DMSO) in the generation of superoxide radical which is a vital intermediate for the transformation. This study also highlights the role of air as the oxidant in the oxidation process. Further, the practical application of the strategy has also been demonstrated for the oxidation of the alc. moiety in cholesterol. In addition to this study using (4-Bromophenyl)methanol, there are many other studies that have used (4-Bromophenyl)methanol(cas: 873-75-6Related Products of 873-75-6) was used in this study.
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Related Products of 873-75-6 It undergoes efficient trimethylsilylation reaction with 1,1,1,3,3,3-hexamethyldisilazane in the presence of catalytic amount of aspartic acid in acetonitrile.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts