《Catalyst-Free N-Deoxygenation by Photoexcitation of Hantzsch Ester》 was written by Konev, Mikhail O.; Cardinale, Luana; Jacobi von Wangelin, Axel. Name: Oxetan-3-ol And the article was included in Organic Letters in 2020. The article conveys some information:
A mild and operationally simple protocol for the deoxygenation of a variety of heteroaryl N-oxides and nitroarenes has been developed. A mixture of substrate and Hantzsch ester is proposed to result in an electron donor-acceptor complex, which upon blue-light irradiation undergoes photoinduced electron transfer between the two reactants to afford the products. N-oxide deoxygenation is demonstrated with 22 examples of functionally diverse substrates, and the chemoselective reduction of nitroarenes to the corresponding hydroxylamines is also shown.Oxetan-3-ol(cas: 7748-36-9Name: Oxetan-3-ol) was used in this study.
Oxetan-3-ol(cas: 7748-36-9) is used as a reagent in the synthesis of 5-fluoro-4,6-dialkoxypyrimidine GPR119 agonists. It is also used as a reagent in the synthesis of cyclic sulfone hydroxyethylamines as potent and selective β-site APP-cleaving enzyme 1 (BACE1) inhibitors.Name: Oxetan-3-ol
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