In 2019,Inorganica Chimica Acta included an article by Elmas, Gamze; Okumus, Aytug; Hokelek, Tuncer; Kilic, Zeynel. Related Products of 156-87-6. The article was titled 《Phosphorus-nitrogen compounds. Part 52. The reactions of octachlorocyclotetraphosphazene with sodium 3-(N-ferrocenylmethylamino)-1-propanoxide: Investigations of spectroscopic, crystallographic and stereogenic properties》. The information in the text is summarized as follows:
The reaction of octachlorocyclotetraphosphazene (tetramer, N4P4Cl8, 1) with two mole equivalent of Na 3-(N-ferrocenylmethylamino)-1-propanoxide (2) gave the novel ansa-spiro (3), 2-trans-6-dispiro (4), 2-cis-6-dispiro (5), 2-trans-4-dispiro (6) and 2-cis-4-dispiro (7) cyclotetraphosphazenes. However, when the reaction was carried out with 1 and three mole equivalent of 2, seven products observed with respect to the 31P NMR spectrum of the reaction mixture Five of these products were identified as 3, 4, 5, 6 and 7, and the other two products are expected to be 2-trans-4-trans-6-trispiro (8) derived from 4 and/or 6, and 2-trans-4-cis-6-trispiro (9) derived from 5 and/or 7. Both of the trispiro products (8 and 9) were not isolated using column chromatog. Besides, when the reaction was made with 1 and excess amount of 2, the tetraspiro products were not observed by TLC and 31P NMR spectrum of the reaction mixture The structures of cyclotetraphosphazene derivatives were verified by ESI-MS, FTIR, 1H, 13C and 31P NMR spectral data. The mol. and solid state structures of 3, 5 and 6 were established by x-ray diffraction method. The x-ray crystallog. data indicate that compounds 3 and 6 have three-different and two equivalent chiral P centers, resp. The absolute configurations of 3 and 6 also are as SS’S” and RR. After reading the article, we found that the author used 3-Aminopropan-1-ol(cas: 156-87-6Related Products of 156-87-6)
3-Aminopropan-1-ol(cas: 156-87-6) belongs to anime. Hydrogen peroxide (H2O2) and peroxy acids generally add an oxygen atom to the nitrogen of amines. With primary amines, this step is normally followed by further oxidation, leading to nitroso compounds, RNO, or nitro compounds, RNO2. Secondary amines are converted to hydroxylamines, R2NOH, and tertiary amines to amine oxides, R3NO.Related Products of 156-87-6
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