The author of 《Manganese(I)-Catalyzed α-Alkenylation of Ketones Using Primary Alcohols》 were Gawali, Suhas Shahaji; Pandia, Biplab Keshari; Gunanathan, Chidambaram. And the article was published in Organic Letters in 2019. Recommanded Product: (4-Bromophenyl)methanol The author mentioned the following in the article:
A simple protocol of manganese catalyzed selective α-alkenylation of ketones using primary alcs. is reported. The reactions proceeded well with a low loading of catalyst (0.3 mol%). The overall transformation operates through O-H bond activation of primary alcs. via dearomatization-aromatization metal ligand cooperation in the catalyst to provide the corresponding aldehydes, which further undergo condensation with methylene ketones to deliver α,β-unsaturated ketones. This selective α-alkenylation proceeds with the release of water and liberation of mol. hydrogen. In the experiment, the researchers used many compounds, for example, (4-Bromophenyl)methanol(cas: 873-75-6Recommanded Product: (4-Bromophenyl)methanol)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Recommanded Product: (4-Bromophenyl)methanol It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts