In 2022,Robinson, Donovan J.; Ortiz, Kacey G.; O’Hare, Nathan P.; Karimov, Rashad R. published an article in Organic Letters. The title of the article was 《Dearomatization of Heteroarenium Salts with ArBpin Reagents. Application to the Total Synthesis of a Nuphar Alkaloid》.Recommanded Product: 24388-23-6 The author mentioned the following in the article:
Rhodium-catalyzed enantioselective addition of aryl and heteroaryl boron pinacol esters to pyridinium and quinolinium salts were developed for the synthesis of enantioenriched dihydroheteroarenes. The methodol. was enabled the synthesis of 2-heteroaryl-substituted dihydropyridines in high yield and ee, which provided efficient synthetic access to a nuphar alkaloid.4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane(cas: 24388-23-6Recommanded Product: 24388-23-6) was used in this study.
4,4,5,5-Tetramethyl-2-phenyl-1,3,2-dioxaborolane(cas: 24388-23-6) can be used as a substrate in the study of Suzuki–Miyaura coupling of various aryl iodides over SiliaCat Pd(0).Recommanded Product: 24388-23-6
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