Cubane Arrives on the Cucurbituril Scene was written by Jelinkova, Kristyna; Surmova, Heda; Matelova, Alena; Rouchal, Michal; Pruckova, Zdenka; Dastychova, Lenka; Necas, Marek; Vicha, Robert. And the article was included in Organic Letters on May 19,2017.Quality Control of Cubane-1,4-diyldimethanol The following contents are mentioned in the article:
Cubane, an intriguing chem. curiosity first studied in the early 1960s, has become a valuable structural motif and has recently been involved in the structures of a great number of prospective compounds The first dicationic supramol. guest 5 is prepared and derived from a 1,4-disubstituted cubane moiety, and its binding behavior toward cucurbit[n]urils (CBn) and cyclodextrins (CD) is studied. The bisimidazolium salt 5 forms 1:1 inclusion complexes with CB7, CB8, and β-CD with the resp. association constants (6.7 ± 0.5) × 1011 M-1, (1.5 ± 0.2) × 109 M-1, and <102 M-1 in water. The solid-state structures of the 5@CB7 and 5@CB8 complexes are also reported. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Quality Control of Cubane-1,4-diyldimethanol).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Quality Control of Cubane-1,4-diyldimethanol
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