Synthesis and structures of 1,4-bis(chloromethyl)-and 1,4-bis(bromomethyl)cubanes was written by Shastin, A. V.; Romanova, L. B.; Eremenko, L. T.; Zakharov, V. V.; Lagodzinskaya, G. V.; Aleksandrov, G. G.; Eremenko, I. L.. And the article was included in Russian Chemical Bulletin on August 31,2006.Recommanded Product: Cubane-1,4-diyldimethanol The following contents are mentioned in the article:
1,4-Bis(chloromethyl)cubane (I) and 1,4-bis(bromomethyl)cubane (II) were synthesized by the reactions of triphenylphosphine with CCl4 and NBS, resp. The structures of the compounds were studied by X-ray diffraction anal. of I [monoclinic, P2(1)/c, a 6.035(12), b 7.365(17), c 11.49(3) Å, β 104.67(10)°, V 494(2) Å3, Z 2] and II [monoclinic, P2(1)/c, a 5.332(3), b 11.074(7), c 7.787(4) Å, β 105.83(4)°, V 442.3(4) Å3, Z 2]. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Recommanded Product: Cubane-1,4-diyldimethanol).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Recommanded Product: Cubane-1,4-diyldimethanol
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