Alkynylcubanes as Precursors of Rigid-Rod Molecules and Alkynylcyclooctatetraenes was written by Eaton, Philip E.; Galoppini, Elena; Gilardi, Richard. And the article was included in Journal of the American Chemical Society on August 24,1994.COA of Formula: C10H12O2 The following contents are mentioned in the article:
The authors have developed new methodol. for the synthesis of alkynylcubanes and have used these compounds to make rigid-rod mols. constructed of cubane and acetylene subunits. Terminal and substituted alkynylcubanes, e.g., ethynylcubane, were synthesized by n-BuLi-promoted elimination of halogen from dibromovinylcubanes, e.g., (2,2-dibromovinyl)cubane, followed by quenching with electrophiles. Systems with one or two acetylenic units between two cubanes were also prepared Dimerizations and cross-coupling reactions of various 1,4-diethynylcubanes afforded longer rods. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3COA of Formula: C10H12O2).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.COA of Formula: C10H12O2
60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3