Electron in a cube: synthesis and characterization of perfluorocubane as an electron acceptor was written by Sugiyama, Masafumi; Akiyama, Midori; Yonezawa, Yuki; Komaguchi, Kenji; Higashi, Masahiro; Nozaki, Kyoko; Okazoe, Takashi. And the article was included in Science (Washington, DC, United States) on August 12,2022.Computed Properties of C10H12O2 The following contents are mentioned in the article:
The synthesis and characterization of perfluorocubane, a stable polyhedral fluorocarbon was reported. The key to the successful synthesis was the efficient introduction of multiple fluorine atoms to cubane by liquid-phase reaction with fluorine gas. The solid-state structure of perfluorocubane was confirmed using x-ray crystallog., and its electron-accepting character was corroborated electrochem. and spectroscopically. The radical anion of perfluorocubane was examined by matrix-isolation ESR spectroscopy, which revealed that the unpaired electron accepted by perfluorocubane is located predominantly inside the cage. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Computed Properties of C10H12O2).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Computed Properties of C10H12O2
60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3