Synthesis of isoxazolo[60]fullerenes with dumb-bell-type structure and atropisomeric properties was written by Irngartinger, Hermann; Weber, Anton; Escher, Thomas; Fettel, Peter Walter; Gassner, Franz. And the article was included in European Journal of Organic Chemistry on September 30,1999.Category: alcohols-buliding-blocks The following contents are mentioned in the article:
Dumb-bell-type fullerene adducts were synthesized via bifunctional nitrile oxides. A cubane-bridged [60]fullerene of this type was synthesized by 2-fold esterification of cubanedimethanol with an isoxazolo[60]fullerene-carboxylate. When a bulky spacer between the fullerene units was used, atropisomers occurred. A fullerene derivative with an anthracene moiety exhibited axial chirality. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Category: alcohols-buliding-blocks).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Category: alcohols-buliding-blocks
60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3