The preparation and fate of cubylcarbinyl radicals was written by Eaton, Philip E.; Yip, Yu Chi. And the article was included in Journal of the American Chemical Society on September 25,1991.Application of 60462-27-3 The following contents are mentioned in the article:
The cubylcarbinyl radical was generated from cubylcarbinyl bromide and from the N-hydroxy-2-pyridinethione ester of cubylacetic acid under various conditions favoring hydrogen-atom transfer to the radical. Only when selenophenol in high concentration is used as the hydrogen donor is any methylcubane formed. Otherwise the cubylcarbinyl radical rearranges. A mechanistic scheme accounting for their formation is presented; sequential σ-bond breaking occurs regioselectively, favoring processes in which there is good overlap between the radical orbital and that of the breaking bond. The rate constant for ring cleavage of cubylcarbinyl radical was calculated to be >2 × 1010 s-1, substantially greater than that of any radical derived to date from a saturated hydrocarbon system. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Application of 60462-27-3).
Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Application of 60462-27-3
60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3